Phase diagrams of knotted and unknotted ring polymers.
نویسندگان
چکیده
The phase diagram for a lattice ring polymer under applied force, with variable solvent quality, for different topological knot states, is determined for the first time. In addition to eliminating pseudophases where the polymer is flattened into a single layer, it is found that nontrivial knots result in additional pseudophases under tensile force conditions.
منابع مشابه
Architecture-Induced Size Asymmetry and Effective Interactions of Ring Polymers: Simulation and Theory
We investigate, by means of Monte Carlo simulations, the role of ring architecture and topology on the relative sizes of two interacting polymers as a function of the distance between their centers-of-mass. As a general rule, polymers swell as they approach each other, irrespectively of their topologies. For each mutual separation, two identical linear polymers adopt the same average size. Howe...
متن کاملEffects of Knots on Ring Polymers in Solvents of Varying Quality
We employ extensive computer simulations to investigate the conformations and the interactions of ring polymers under conditions of worsening solvent quality, in comparison with those for linear polymers. We determine the dependence of the Θ-temperature on knotedness by considering ring polymers of different topologies. We establish a clear decrease of the former upon changing the topology of t...
متن کاملPulling knotted polymers
– We compare Monte Carlo simulations of knotted and unknotted polymers whose ends are connected to two parallel walls. The force f exerted on the polymer is measured as a function of the separation R between the walls. For unknotted polymers of several monomer numbers N , the product fN is a simple function of R/N , where ν 0.59. By contrast, knotted polymers exhibit strong finite-size effects ...
متن کاملKnots modify the coil-stretch transition in linear DNA polymers.
We perform single-molecule DNA experiments to investigate the relaxation dynamics of knotted polymers and examine the steady-state behavior of knotted polymers in elongational fields. The occurrence of a knot reduces the relaxation time of a molecule and leads to a shift in the molecule's coil-stretch transition to larger strain rates. We measure chain extension and extension fluctuations as a ...
متن کاملKnotted vs. Unknotted Proteins: Evidence of Knot-Promoting Loops
Knotted proteins, because of their ability to fold reversibly in the same topologically entangled conformation, are the object of an increasing number of experimental and theoretical studies. The aim of the present investigation is to assess, on the basis of presently available structural data, the extent to which knotted proteins are isolated instances in sequence or structure space, and to us...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review. E, Statistical, nonlinear, and soft matter physics
دوره 85 3 Pt 1 شماره
صفحات -
تاریخ انتشار 2012